杨海斌,汪旭光,王尹军,张建如
YANG Hai-bin,WANG Xu-guang,WANG Yin-jun,ZHANG Jian-ru

• 1:中国矿业大学(北京)力学与建筑工程学院
• 2:河北云山化工集团有限公司
• 3:矿冶科技集团有限公司

摘要(Abstract)：

为研究新研制的CO_2相变爆炸激发药剂的爆炸性与安全性，采用克南试验方法进行了激发药剂的爆炸性能测试，并分别用8号工业雷管和150～500 g膨化硝铵炸药，对直径50 mm和90 mm的2 kg塑膜包装激发药剂药卷进行引爆试验。试验结果表明，由高氯酸钾、水杨酸和草酸铵按照一定比例组成的激发药剂具有爆炸性，但其爆轰感度很低，不仅没有雷管起爆感度，而且无法用膨化硝铵炸药将其引爆，与粒状铵油炸药相比，爆轰感度低、安全性好。
In order to study the explosiveness and safety of the newly developed excitation agent for CO_2 phase change explosion, the explosive performance test of the excitation agent was carried out by using the Kenan test method, and the 2 kg plastic film packed excitation agent rolls with diameters of 50 mm and 90 mm were initiated by No. 8 industrial detonator and 150-500 g expanded ammonium nitrate explosives respectively. The test results show that the excitation agent composed of potassium perchlorate, salicylic acid and ammonium oxalate in a certain proportion is explosive, but its detonation sensitivity is very low. It has no detonator initiation sensitivity, and cannot be detonated with the expanded ammonium nitrate explosives. Compared with the granular ammonium fried explosive, it has lower detonation sensitivity and is much safer.

关键词(KeyWords)： CO_2相变爆炸;激发药剂;克南试验;爆炸性;爆轰感度;钝感
CO_2 phase change explosion;excitation;Kernan test;explosiveness;detonation sensitivity;insensitivity

Abstract:

Keywords:

基金项目(Foundation):

作者(Author): 杨海斌,汪旭光,王尹军,张建如
YANG Hai-bin,WANG Xu-guang,WANG Yin-jun,ZHANG Jian-ru

DOI: 10.19931/j.EB.20210335

参考文献(References)：

• [1] 樊浩.二氧化碳爆破对煤岩破坏特征研究[D].西安：西安科技大学，2018.PAN H.Study on the damage characteristics of coal and rock by carbon dioxide blasting[D].Xi'an:Xi'an University of Science and Technology,2018.
• [2] SATO M,HOSHINA Y,HANAI M.Dielectric properties in high pressure CO2 and N2 gas using coaxial cylindrical electrode and on the surface of spacer [C]//IEEE.Piscataway ,NJ,USA ,2002.
• [3] FRANKE H ,THIEL H G.Theoretical and diagnostic investigation of gas blast ,turbulence controlled arcs in circuit breakers [ J ].Elektrotechnische Zeitschrift ETZ A,1971 ,92(5):298-302.
• [4] 杜泽生，范迎春，薛宇飞，等.二氧化碳爆破采掘装备及技术研究[J].煤炭科学技术，2016,44(9):36-42.DU Z S,FAN Y C,XUE Y F,et al.Study on carbon dioxide blasting mining and driving equipment and technology[J].Coal Science and Technology,2016,44(9):36-42.
• [5] 周西华，门金龙，宋东平，等.液态CO2爆破煤层增透最优钻孔参数研究[J].岩石力学与工程学报，2016(3):524-529.ZHOU X H,MEN J L,SONG D P,et al.Research on optimal borehole parameters of antireflection in coal seam by liquid CO2 blasting[J].Chinese Journal of Rock Mechanics and Engineering,2016(3):524-529.
• [6] 张家行.二氧化碳致裂技术及在煤矿安全生产中的应用研究[D].北京：煤炭科学研究总院研究生院，2017.ZHANG J X.Research on carbon dioxide cracking technology and its application in coal mine safety production [D].BejJing:Graduate School of General Coal Research Institute,2017.
• [7] 张开加.不同埋深条件下二氧化碳致裂爆破技术增透效果试验研究[J].中国煤炭，2018,44(7):110-114,119ZHANG K J.Experimental study on the effect of permeability increasing by carbon dioxide blasting technology under different buried depth conditions[J].China Coal,2018,44(7):110-114,119.
• [8] 杨百舸，张军胜，令狐建设，等.突出煤层 CO2气相压裂高效抽采防突掘进技术[J].煤田地质与勘探，2021,49(3):85-94.YANG B G,ZHANG J S,LINGHU J S,et al.An advanced CO2 gas-phase fracturing technology for efficient methane drainage,outburst prevention and excavation in outburst coal seam[J].Coal Geology & Exploration,2021,49(3):85-94.
• [9] 方鹏.斜沟煤矿18205工作面CO2致裂增透最优钻孔布置参数研究[J].煤，2020,29(2):11-14,17.FANG P.Optimal drilling parameters of CO2 fracturing and permeability increasing in 18205 working face of xiegou coal mine[J].Coal,2020,29(2):11-14,17.
• [10] 李稳，陈颙，王夫运，等.二氧化碳相变技术应用于新型震源研发的可行性研究[J].地球物理学报，2020,63(7):2 605-2 616.LI W,CHEN Y,WANG F Y,et al.Feasibility study of developing one new type of seismic source via carbon dioxide phasetransition[J].Chinese J.Geophys,2020,63(7):2 605-2 616.
• [11] 夏军，陶良云，李必红，等.CO2液-气相变膨胀破岩技术及应用[J].工程爆破，2018,24(3):50-54.XIA J,TAO L Y,LI B H,et al.Technology and application of the rock breaking by CO2 liquid-gas phase transition and expansion[J].Engineering Blasting,2018,24 (3):50-54.
• [12] 龚政.CO2膨胀破岩技术在拆除工程中的应用[J].广东水利水电.2020(9):89-92.GONG Z.Application of rock-breaking by CO2 technology in demolition engineering [J] .Guangdong Water Conservancy and Hydropower,2020(9):89-92.
• [13] 李世安.二氧化碳致裂技术在地铁车站基坑开挖中的应用[J].市政技术，2020,38(4):258-262,273.LI S A.Application of carbon dioxide cracking technology in foundation pit excavation of subway station[J].Municipal Technology,2020,38 (4):258-262,273.
• [14] 熊宏武.液态二氧化碳爆破法在综合管廊开挖中的应用[J].铁道建筑技术，2020(12):135-139.XIONG H W.Application of liquid carbon dioxide blasting method in excavation of utility tunnel[J].Railway Construction Technology,2020(12):135-139.
• [15] 丁海龙，刘典忠，娄旭峰，等.高海拔地区工程项目应用二氧化碳致裂技术浅析[J].四川水利，2020(5):14-17.DING H L,LIU D Z,LOU X F,et al.Analysis on the application of carbon dioxide cracking technology in engineering projects in high altitude areas [J].Sichuan Water Conservancy,2020(5):14-17.
• [16] 董云涛，董庆祥，谢雨航，等.液体二氧化碳相变致裂技术在处置电石炉电极软断中的应用[J].科学技术创新，2020(26):65-66.DONG Y T,DONG Q X,XIE Y H,et al.Application of liquid carbon dioxide phase change cracking technology in the treatment of calcium carbide furnace electrode soft break [J].Scientific and Technological Innovation,2020(26):65-66.
• [17] 王燕，孙伟博，张丁丁.二氧化碳相变致裂软岩实验研究[J].爆破器材，2020,49(2):46-51.WANG Y ,SUN W B,ZHANG D D.Experimental study on fracture of soft rock fracturing by phase change of carbon dioxide[J].Explosive Materials,2020,49(2):46-51.
• [18] 赵程鹏，商武锋，许小泉，等.液态 CO2相变开挖岩体孔间距参数研究[J].工程爆破，2021,27(3):74-82.ZHAO C P,SHANG W F,XU X Q,et al.Study on borehole spacing parameters of rock excavation by liquid CO2 phase change[J].Engineering Blasting,2021,27(3):74-82.
• [19] 衡献伟，付金磊，李青松，等.液态 CO2相变致裂对抽采有效半径影响的试验研究 [J].煤炭工程，2021,53(10):126-130.HENG X W,FU J L,LI Q S,et al.Experimental study on influence of liquid CO2 phase change fracturing on effective extraction radius [J].Coal Engineering,2021,53(10):126-130.
• [20] 赵丹，刘晓青.液态 CO2煤层增透技 术及 应用 研究[J].煤炭 科学 技术，2021,49 (10):107-114.ZHAO D,LIU X Q.Research and application of anti-reflection technology of liquid CO2 coal seam[J].Coal Science and Technology,2021,49( 10):107-114.
• [21] 李青松，付金磊，衡献伟，等.基于 CO2相变致裂技术的低渗透煤层钻孔参数优化研究[J].煤炭技术，2021,40(11):118-123.LI Q S,FU J L,HENG X W,et al.Research on optimization of drilling parameters in low permeability coal seam based on CO2 phase change fracturing[J].Coal Technology,2021,40(11):118-123.
• [22] 白鑫，骆桂君，王艳，等.低渗砂岩型铀矿液态CO2相变致裂增透高效开采新模式[J].金属矿山，2021(7):50-57.BAI X,LUO G J,WANG Y,et al.Feasibility study on enhanced permeability of low permeability sandstone type uranium deposit with liquid CO2 phase transition fracturing[J].Metal Mine,2021(7):50-57.
• [23] 朱宽，徐添福，刘保阳，等.二氧化碳膨胀爆破不同步影响因素探究[J].采矿技术，2021,21(1):116-120.ZHU K,XU T F,LIU B Y,et al.Study on the factors affecting the asynchrony of carbon dioxide expansion blasting[J].Mining Technology,2021,21(1):116-120.
• [24] 贾进章，柯丁琳，李斌.液态 CO2爆破钻孔布置参数优化[J].辽宁工程技术大学学报(自然科学版),2021,40(2):97-103.JIA J Z,KE D L,LI B.Optimization of increasing permeability technical parameters of CO2 phase change blasting[J].Journal of Liaoning Technical University (Natural science),2021,40(2):97-103.
• [25] 李维.液态CO2爆破技术在邻近边坡基坑开挖中的模拟研究[J].采矿技术，2022 ,22 (3):162-167.LI W.Simulation study of liquid CO2 blasting technology in foundation pit excavation of adjacent slope[J].Mining Technology,2022 ,22(3):162-167.
• [26] 郭超，刘玲，李娟.基于最小自由能原理的二氧化碳致裂器发热材料危险性研究[J].采矿技术，2018,18(5):235-237.GUO C,LIU L,LI J.Study on the risk of heating materials of carbon dioxide crack maker based on the principle of minimum free energy [J].Mining Technology,2018,18(5):235-237.